Influences of mechanical activation and tartaric acid addition on the efficiency of B4C synthesis

  • Seyed Faridaddin Feiz 1
  • Leila Nikzad 1
  • Hudsa Majidian 1
  • Esmaeil Salahi 1
  • 1 Ceramics Department, Materials and Energy Research Center (MERC), Karaj, Iran

Abstract

In this paper, mechanical activation and tartaric acid addition were employed to reduce the residual carbon and intensify the efficiency of B4C synthesis using glucose and boric acid as starting materials. To investigate the role of mechanical activation on synthesis performance, one sample was subjected to high-energy ball milling before pyrolysis and the other after pyrolysis. To study the role of additives, in the precursor production stage, on synthesis efficiency and residual carbon reduction, different amounts of tartaric acid (0, 5, 10, 25, and 50 wt%) were tested. FT-IR and XRD analyses were used to characterize the bonds created in the precursors and the phases formed during the pyrolysis and synthesis steps, respectively. The results confirmed that mechanical activation before synthesis can improve the synthesis efficiency, but ball milling before pyrolysis did not significantly affect the final synthesis product. The addition of tartaric acid enhanced the formation of B–C bonds; hence, it increased the efficiency of B4C synthesis. The optimum additive amount was 25 wt% and higher amounts weakened the synthesis performance.

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Keywords: B4C, Synthesis efficiency, Mechanical activation, Tartaric acid addition, Residual carbon

References

[1] H. Biçer, M. Tuncer, Conventional and two-step sintering of boron carbide ceramics with a sintering additive, J. Aust. Ceram. Soc. 58 (2022) 21–27. https://doi.org/10.1007/s41779-021-00661-7.
[2] W. Zhang, A novel ceramic with low friction and wear toward tribological applications: Boron carbide-silicon carbide, Adv. Colloid Interface Sci. 301 (2022) 102604. https://doi.org/10.1016/j.cis.2022.102604.
[3] V. Özkan Bilici, Ultrasonic properties of Ni–Fe–B4C cermets produced by tube furnace sintering, Synth. Sinter. 2 (2022) 62–66. https://doi.org/10.53063/synsint.2022.2287.
[4] A. Arumugam, P. Lakshmanan, S. Palani, Micro groove cutting on the surfaces of Cu-B4C nanocomposites by fiber laser, Surf. Topogr. Metrol. Prop. 9 (2021) 035023. https://doi.org/10.1088/2051-672X/ac1c7f.
[5] O.N. Baklanova, A.V. Vasilevich, A.V. Lavrenov, V.A. Drozdov, I.V. Muromtsev, et al., Molybdenum carbide synthesized by mechanical activation an inert medium, J. Alloys Compd. 698 (2017) 1018–1027. https://doi.org/10.1016/j.jallcom.2016.12.186.
[6] A. Najafi, F. Golestani-Fard, H.R. Rezaie, Sol-gel synthesis and characterization of B4C nanopowder, Ceram. Int. 44 (2018) 21386–21394. https://doi.org/10.1016/j.ceramint.2018.08.196.
[7] P. Asgarian, A. Nourbakhsh, P. Amin, R. Ebrahimi-Kahrizsangi, K.J.D. MacKenzie, The effect of different sources of porous carbon on the synthesis of nanostructured boron carbide by magnesiothermic reduction, Ceram. Int. 40 (2014) 16399–16408. https://doi.org/10.1016/j.ceramint.2014.07.147.
[8] M.K. Zakaryan, A.R. Zurnachyan, N.H. Amirkhanyan, H.V. Kirakosyan, M. Antonov, et al., Novel pathway for the combustion synthesis and consolidation of boron carbide, Materials (Basel). 15 (2022) 5042. https://doi.org/10.3390/ma15145042.
[9] A. Alizadeh, E. Taheri-Nassaj, N. Ehsani, Synthesis of boron carbide powder by a carbothermic reduction method, J. Eur. Ceram. Soc. 24 (2004) 3227–3234. https://doi.org/10.1016/j.jeurceramsoc.2003.11.012.
[10] C.-H. Jung, M.-J. Lee, C.-J. Kim, Preparation of carbon-free B4C powder from B2O3 oxide by carbothermal reduction process, Mater. Lett. 58 (2004) 609–614. https://doi.org/10.1016/S0167-577X(03)00579-2.
[11] I. Yanase, R. Ogawara, H. Kobayashi, Synthesis of boron carbide powder from polyvinyl borate precursor, Mater. Lett. 63 (2009) 91–93. https://doi.org/10.1016/j.matlet.2008.09.012.
[12] D. Davtyan, R. Mnatsakanyan, L. Liu, S. Aydinyan, I. Hussainova, Microwave synthesis of B4C nanopowder for subsequent spark plasma sintering, J. Mater. Res. Technol. 8 (2019) 5823–5832. https://doi.org/10.1016/j.jmrt.2019.09.052.
[13] L. Shi, Y. Gu, L. Chen, Y. Qian, Z. Yang, J. Ma, A low temperature synthesis of crystalline B4C ultrafine powders, Solid State Commun. 128 (2003) 5–7. https://doi.org/10.1016/S0038-1098(03)00627-6.
[14] A. Chakraborti, N. Vast, Y. Le Godec, Synthesis of boron carbide from its elements at high pressures and high temperatures, Solid State Sci. 104 (2020) 106265. https://doi.org/10.1016/j.solidstatesciences.2020.106265.
[15] A. Chakraborti, N. Guignot, N. Vast, Y. Le Godec, Synthesis of boron carbide from its elements up to 13 GPa, J. Phys. Chem. Solids. 159 (2021) 110253. https://doi.org/10.1016/j.jpcs.2021.110253.
[16] A.K. Suri, C. Subramanian, J.K. Sonber, T.S.R.C. Murthy, Synthesis and consolidation of boron carbide: a review, Int. Mater. Rev. 55 (2010) 4–40. https://doi.org/10.1179/095066009X12506721665211.
[17] Ö.D. Eroğlu, N.A. Sezgi, H. ö. Özbelge, H.H. Durmazuçar, Synthesis and characterization of boron carbide films by plasma-enhanced chemical vapor deposition, Chem. Eng. Commun. 190 (2003) 360–372. https://doi.org/10.1080/00986440302136.
[18] N. Shawgi, S. Li, S. Wang, A Novel method of synthesis of high purity nano plated boron carbide powder by a solid-state reaction of poly (vinyl alcohol) and boric acid, Ceram. Int. 43 (2017) 10554–10558. https://doi.org/10.1016/j.ceramint.2017.05.120.
[19] R. Belon, G. Antou, N. Pradeilles, A. Maître, D. Gosset, Mechanical behaviour at high temperature of spark plasma sintered boron carbide ceramics, Ceram. Int. 43 (2017) 6631–6635. https://doi.org/10.1016/j.ceramint.2017.02.053.
[20] F. Farzaneh, F. Golestanifard, M.S. Sheikhaleslami, A.A. Nourbakhsh, New route for preparing nanosized boron carbide powder via magnesiothermic reduction using mesoporous carbon, Ceram. Int. 41 (2015) 13658–13662. https://doi.org/10.1016/j.ceramint.2015.07.163.
[21] T. Kobayashi, K. Yoshida, T. Yano, Effects of heat-treatment temperature and starting composition on morphology of boron carbide particles synthesized by carbothermal reduction, Ceram. Int. 39 (2013) 597–603. https://doi.org/10.1016/j.ceramint.2012.06.070.
[22] A. Gubernat, W. Pichór, D. Zientara, M.M. Bućko, Ł. Zych, D. Kozień, Direct synthesis of fine boron carbide powders using expanded graphite, Ceram. Int. 45 (2019) 22104–22109. https://doi.org/10.1016/j.ceramint.2019.07.227.
[23] O. Karaahmet, B. Cicek, Effect of mechanically modification process on boron carbide synthesis from polymeric precursor method, Ceram. Int. 48 (2022) 11940–11952. https://doi.org/10.1016/j.ceramint.2022.01.043.
[24] M. Kakiage, Low-temperature synthesis of boride powders by controlling microstructure in precursor using organic compounds, J. Ceram. Soc. Jpn. 126 (2018) 602–608. https://doi.org/10.2109/jcersj2.18093.
[25] M. Kakiage, N. Tahara, I. Yanase, H. Kobayashi, Low-temperature synthesis of boron carbide powder from condensed boric acid–glycerin product, Mater. Lett. 65 (2011) 1839–1841. https://doi.org/10.1016/j.matlet.2011.03.046.
[26] Rafi-ud-din, G.H. Zahid, Z. Asghar, M. Maqbool, E. Ahmad, et al., Ethylene glycol assisted low-temperature synthesis of boron carbide powder from borate citrate precursors, J. Asian Ceram. Soc. 2 (2014) 268–274. https://doi.org/10.1016/j.jascer.2014.05.011.
[27] S. Wang, Y. Li, X. Xing, X. Jing, Low-temperature synthesis of high-purity boron carbide via an aromatic polymer precursor, J. Mater. Res. 33 (2018) 1659–1670. https://doi.org/10.1557/jmr.2018.97.
[28] S.F. Feiz, L. Nikzad, H. Majidian, E. Salahi, Performance of glucose, sucrose and cellulose as carbonaceous precursors for the synthesis of B4C powders, Synth. Sinter. 2 (2022) 26–30. https://doi.org/10.53063/synsint.2022.21108.
[29] S.F. Feiz, L. Nikzad, H. Majidian, E. Salahi, Effects of glucose pretreatment and boric acid content on the synthesizability of B4C ceramics, Synth. Sinter. 2 (2022) 78–83. https://doi.org/10.53063/synsint.2022.22115.
[30] S.F. Feiz, L. Nikzad, H. Majidian, E. Salahi, Optimum temperature, time and atmosphere of precursor pyrolysis for synthesis of B4C ceramics, Synth. Sinter. 2 (2022) 146–150. https://doi.org/10.53063/synsint.2022.23119.
[31] S.F. Feiz, L. Nikzad, H. Majidian, E. Salahi, Synthesizability improvement of B4C ceramics by optimizing the process temperature and atmosphere, Synth. Sinter. 2 (2022) 181–185. https://doi.org/10.53063/synsint.2022.24131.
[32] Y.W. Sitotaw, N.G. Habtu, A.Y. Gebreyohannes, S.P. Nunes, T. Van Gerven, Ball milling as an important pretreatment technique in lignocellulose biorefineries: a review, Biomass Convers. Biorefinery. 13 (2021) 15593–15616. https://doi.org/10.1007/s13399-021-01800-7.
[33] J. Joy, A. Krishnamoorthy, A. Tanna, V. Kamathe, R. Nagar, S. Srinivasan, Recent developments on the synthesis of nanocomposite materials via ball milling approach for energy storage applications, Appl. Sci. 12 (2022) 9312. https://doi.org/10.3390/app12189312.
[34] M. Nuruddin, M. Hosur, M.J. Uddin, D. Baah, S. Jeelani, A novel approach for extracting cellulose nanofibers from lignocellulosic biomass by ball milling combined with chemical treatment, J. Appl. Polym. Sci. 133 (2016) 42990. https://doi.org/10.1002/app.42990.
[35] F. Salver-Disma, C. Lenain, B. Beaudoin, L. Aymard, J.-M. Tarascon, Unique effect of mechanical milling on the lithium intercalation properties of different carbons, Solid State Ion. 98 (1997) 145–158. https://doi.org/10.1016/S0167-2738(97)00108-2.
[36] M. Wei, B. Wang, M. Chen, H. Lyu, X. Lee, et al., Recent advances in the treatment of contaminated soils by ball milling technology: Classification, mechanisms, and applications, J. Clean. Prod. 340 (2022) 130821. https://doi.org/10.1016/j.jclepro.2022.130821.
[37] D. Zhong, K. Zeng, J. Li, Y. Qiu, G. Flamant, et al., Characteristics and evolution of heavy components in bio-oil from the pyrolysis of cellulose, hemicellulose and lignin, Renew. Sustain. Energy Rev. 157 (2022) 111989. https://doi.org/10.1016/j.rser.2021.111989.
[38] A. Paajanen, A. Rinta-Paavola, J. Vaari, High-temperature decomposition of amorphous and crystalline cellulose: reactive molecular simulations, Cellulose. 28 (2021) 8987–9005. https://doi.org/10.1007/s10570-021-04084-2.
[39] A. Al-Rumaihi, M. Shahbaz, G. Mckay, H. Mackey, T. Al-Ansari, A review of pyrolysis technologies and feedstock: A blending approach for plastic and biomass towards optimum biochar yield, Renew. Sustain. Energy Rev. 167 (2022) 112715. https://doi.org/10.1016/j.rser.2022.112715.
[40] G. Wang, Y. Dai, H. Yang, Q. Xiong, K. Wang, et al., A review of recent advances in biomass pyrolysis, Energy Fuels. 34 (2020) 15557–15578. https://doi.org/10.1021/acs.energyfuels.0c03107.
[41] A. Talimian, V. Pouchly, H.F. El-Maghraby, K. Maca, D. Galusek, Impact of high energy ball milling on densification behaviour of magnesium aluminate spinel evaluated by master sintering curve and constant rate of heating approach, Ceram. Int. 45 (2019) 23467–23474. https://doi.org/10.1016/j.ceramint.2019.08.051.
[42] J.-A. Liu, C.-H. Li, Y. Zou, A.-N. Chen, L. Hu, Y.-S. Shi, Effect of ball milling on the sintering performance of indium-gallium-zinc oxide ceramics: The diffusion mechanism and lattice distortion of milled powders, Ceram. Int. 47 (2021) 15682–15694. https://doi.org/10.1016/j.ceramint.2021.02.138.
[43] M.T. Soe, P. Chitropas, T. Pongjanyakul, E. Limpongsa, N. Jaipakdee, Thai glutinous rice starch modified by ball milling and its application as a mucoadhesive polymer, Carbohydr. Polym. 232 (2020) 115812. https://doi.org/10.1016/j.carbpol.2019.115812.
[44] H. Liu, X. Chen, G. Ji, H. Yu, C. Gao, et al., Mechanochemical deconstruction of lignocellulosic cell wall polymers with ball-milling, Bioresour. Technol. 286 (2019) 121364. https://doi.org/10.1016/j.biortech.2019.121364.
[45] S.S. Paramanantham, B. Brigljević, A. Ni, V.M. Nagulapati, G.-F. Han, et al., Numerical simulation of ball milling reactor for novel ammonia synthesis under ambient conditions, Energy. 263 (2023) 125754. https://doi.org/10.1016/j.energy.2022.125754.
[46] S.P. du Preez, D.G. Bessarabov, On-demand hydrogen generation by the hydrolysis of ball-milled aluminum composites: A process overview, Int. J. Hydrog. Energy. 46 (2021) 35790–35813. https://doi.org/10.1016/j.ijhydene.2021.03.240.
[47] A. Chahardoli, F. Jalilian, Z. Memariani, M.H. Farzaei, Y. Shokoohinia, Analysis of organic acids, Recent Advances in Natural Products Analysis, Elsevier. (2020) 767–823. https://doi.org/10.1016/B978-0-12-816455-6.00026-3.
[48] M. Zhang, X. Zhang, Y. Liu, K. Wu, Y. Zhu, et al., Insights into the relationships between physicochemical properties, solvent performance, and applications of deep eutectic solvents, Environ. Sci. Pollut. Res. 28 (2021) 35537–35563. https://doi.org/10.1007/s11356-021-14485-2.
[49] S. Xie, H.-T. Tran, M. Pu, T. Zhang, Transformation characteristics of organic matter and phosphorus in composting processes of agricultural organic waste: Research trends, Mater. Sci. Energy Technol. 6 (2023) 331–342. https://doi.org/10.1016/j.mset.2023.02.006.
[50] E. Khademian, E. Salehi, H. Sanaeepur, F. Galiano, A. Figoli, A systematic review on carbohydrate biopolymers for adsorptive remediation of copper ions from aqueous environments-part A: Classification and modification strategies, Sci. Total Environ. 738 (2020) 139829. https://doi.org/10.1016/j.scitotenv.2020.139829.

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Influences of mechanical activation and tartaric acid addition on the efficiency of B4C synthesis
Submitted
2023-02-14
Available online
2023-03-29
How to Cite
Feiz, S. F., Nikzad, L., Majidian, H., & Salahi, E. (2023). Influences of mechanical activation and tartaric acid addition on the efficiency of B4C synthesis. Synthesis and Sintering, 3(1), 54-59. https://doi.org/10.53063/synsint.2023.31140