Research article

On the synthesis and sintering behavior of a novel Mg-Ca alloy, Part I: Mechanical alloying

  • Parisa Golmohammadi 1
  • Fatemeh Saljooghi 1
  • Ahmad Bahmani 2
  • Nader Parvin 1
  • Behzad Nayebi 1
  • 1 Department of Materials and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran, Iran
  • 2 Department of Advanced Materials and Renewable Energy, Iranian Research Organization for Science and Technology, Tehran, Iran
https://doi.org/10.53063/synsint.2022.23118

Abstract

A novel Mg-0.7Ca alloy was prepared by the mechanical alloying (MA) process. Different variables were examined in order to obtain the optimum sample with the best milling behavior and potential sinterability. The structural studies were carried out using X-ray Diffractometer (XRD) and scanning electron microscopy (SEM). Crystallite size and lattice strain of the milled samples were examined by Scherrer and Williamson-Hall methods in order to finalize the investigation. The optimum milling time was found to be 60 minutes. In addition, a starch-containing sample with a fraction of 2.5 weight percent seemed to have the best microstructural properties, based on SEM observations and crystallite size assessments. Due discussions about the effective phenomena during the mechanical alloying were also included.

Downloads

Download data is not yet available.
Keywords: Mechanical alloying, Magnesium, Crystallite size, Morphology, Phase analysis

References

[1] C.M.A. Brett, L. Dias, B. Trindade, R. Fischer, S. Mies, Characterisation by EIS of ternary Mg alloys synthesised by mechanical alloying, Electrochim. Acta. 51 (2006) 1752–1760. https://doi.org/10.1016/j.electacta.2005.02.124.
[2] P. Burke, Investigation of the Sintering Fundamentals of Magnesium Powders, PhD thesis, Dalhousie University. (2011).
[3] A. Bahmani, B. Nayebi, S. Bornay Zonoozi, L. Wang, M. Shokouhimehr, Mechanochemical characteristics of Ca-added Mg-based alloys: A multimodality approach, Mater. Charact. 167 (2020) 110475. https://doi.org/10.1016/j.matchar.2020.110475.
[4] A. Das, Spark Plasma Sintering of Magnesium Matrix Camposites, MSc Thesis, Graduate College of the Oklahoma State University. (2012).
[5] H. Danninger, What will be the future of powder metallurgy?, Powder Metall. Prog. 18 (2018) 70–79. https://doi.org/10.1515/pmp-2018-0008.
[6] J.M. Seitz, A. Lucas, M. Kirschner, Magnesium-Based Compression Screws: A Novelty in the Clinical Use of Implants, JOM. 68 (2016) 1177–1182. https://doi.org/10.1007/s11837-015-1773-1.
[7] M.H. Enayati, Z. Sadeghian, M. Salehi, A. Saidi, The effect of milling parameters on the synthesis of Ni3Al-intermetallic compound by mechanical alloying, Mater. Sci. Eng. 375–377 (2004) 809–811. https://doi.org/10.1016/j.msea.2003.10.060.
[8] P.S. Gilman, J.S. Benjamin, Mechanical Alloying, Annu. Rev. Mater. Sci. 13 (1983) 279–300. https://doi.org/10.1146/annurev.ms.13.080183.001431.
[9] C. Suryanarayana, E. Ivanov, V.V. Boldyrev, The science and technology of mechanical alloying, Mater. Sci. Eng. 304–306 (2001) 151–158. https://doi.org/10.1016/S0921-5093(00)01465-9.
[10] M.S. El-Eskandarany, The history and necessity of mechanical alloying, Third Edit. Elsevier Inc. (2015) 13–47. https://doi.org/10.1016/B978-1-4557-7752-5.00002-4.
[11] D. Annur, A. Suhardi, M.I. Amal, M.S. Anwar, I. Kartika, Powder metallurgy preparation of Mg-Ca alloy for biodegradable implant application, J. Phys: Conf. Ser. 817 (2017) 012062. https://doi.org/10.1088/1742-6596/817/1/012062.
[12] H.E. Exner, E. Arzt, Sintering Processes, Physical Metallurgy (Fourth, Revised and Enhanced Edition), North-Holland. (1996) 2627–2662. https://doi.org/10.1016/B978-044489875-3/50036-3.
[13] M. Demuynck, J.P. Erauw, O. Van der Biest, F. Delannay, F. Cambier, Densification of alumina by SPS and HP: A comparative study, J. Eur. Ceram. Soc. 32 (2012) 1957–1964. https://doi.org/10.1016/B978-044489875-3/50036-3.
[14] Y. Cheng, Z. Cui, L. Cheng, D. Gong, W. Wang, Effect of particle size on densification of pure magnesium during spark plasma sintering, Adv. Powder Technol. 28 (2017) 1129–1135. https://doi.org/10.1016/j.apt.2017.01.017.
[15] O. Ozgun, K. Aslantaş, A. Ercetin, Powder Metallurgy Mg-Sn alloys: Production and characterization, Sci. Iran. 27 (2019) 1255–1265. https://doi.org/10.24200/sci.2019.50212.1578.
[16] P.M. Kibasomba, S. Dhlamini, M. Maaza, C.-P. Liu, M.M. Rashad, Strain and grain size of TiO2 nanoparticles from TEM, Raman spectroscopy and XRD: The revisiting of the Williamson-Hall plot method, Results Phys. 9 (2018) 628–635. https://doi.org/10.1016/j.rinp.2018.03.008.
[17] Q. Fang, Z. Kang, An investigation on morphology and structure of Cu-Cr alloy powders prepared by mechanical milling and alloying, Powder Technol. 270 (2015) 104–111. https://doi.org/10.1016/j.powtec.2014.10.010.
[18] C. Suryanarayana, Mechanical Alloying: A Novel Technique to Synthesize Advanced Materials, Research. 2019 (2019) 1–17. https://doi.org/10.34133/2019/4219812.
Scopus
Europe PMC

Cited By

Crossref Google Scholar
On the synthesis and sintering behavior of a novel Mg-Ca alloy, Part I: Mechanical alloying
Submitted
2022-05-30
Published
2022-09-30
How to Cite
Golmohammadi, P., Saljooghi, F., Bahmani, A., Parvin, N., & Nayebi, B. (2022). On the synthesis and sintering behavior of a novel Mg-Ca alloy, Part I: Mechanical alloying. Synthesis and Sintering, 2(3), 131-137. https://doi.org/10.53063/synsint.2022.23118
Issue
Vol. 2 No. 3 (2022)

Copyright (c) 2022 Parisa Golmohammadi, Fatemeh Saljooghi, Ahmad Bahmani, Nader Parvin, Behzad Nayebi

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copyright
Authors are the copyright holders of their published papers in Synthesis and Sintering, which are simultaneously licensed under a Creative Commons Attribution 4.0 International License. The full details of the license are available at https://creativecommons.org/licenses/by/4.0/.

All papers published open access will be immediately and permanently free for everyone to read, download, copy, distribute, print, search, link to the full-text of papers, crawl them for indexing, pass them as data to software, or use them for any other lawful purpose without any registration obstacles or subscription fees.

Most read articles by the same author(s)