Wear behavior of self-propagating high-temperature synthesized Cu-TiO2 nanocomposites

  • Hossein Aghajani 1
  • Mohammad Roostaei 2
  • Shaya Sharif Javaherian 2
  • Arvin Taghizadeh Tabrizi 1
  • Ali Abdoli Silabi 3
  • Navid Farzam Mehr 4
  • 1 School of Metallurgy and Materials Engineering, Iran University of Science & Technology, Narmak, Tehran, Iran
  • 2 Materials Engineering Department, University of Tabriz, Tabriz, Iran
  • 3 Iran Small Industries and Industrial Parks Organization (ISIPO), Tehran, Iran
  • 4 Institut fur Metallurgie, TU Clausthal, Clausthal-Zellerfeld, Germany

Abstract

In this paper, the copper-based nanocomposites with TiO2 nanoparticles were synthesized by the self-propagating high-temperature synthesis (SHS) process. The effect of the different amounts of excess copper, in comparison with the stoichiometric ratio (CuO:Ti ratios of 1:1, 2:1, and 3:1), on the phase formation of achieved samples was studied. A thermodynamical study showed that increasing the excess copper powder reduces the adiabatic temperature, which helps the phase formation. The maximum Brinell hardness (89) was obtained for the sample with the CuO:Ti ratio of 1:1. Finally, the wear behavior of the synthesized nanocomposites was evaluated by the pin on disk test, and the variation of friction coefficient and lost weight were measured. The friction coefficient decreased by the formation of phases and distribution of titanium oxide particles during the SHS process in the presence of the stoichiometric ratio of CuO:Ti. Therefore, the wear behavior was improved. The lowest depth of wear trace was measured 0.68 where the ratio of CuO:Ti was 1:1.

Downloads

Download data is not yet available.
Keywords: Wear behavior, Synthesis, Thermodynamic, Cu-TiO2

References

[1] Z. Zeng, L. Wang, L. Chen, J. Zhang, The correlation between the hardness and tribological behaviour of electroplated chromium coatings sliding against ceramic and steel counterparts, Surf. Coat. Technol. 201 (2006) 2282–2288. https://doi.org/10.1016/j.surfcoat.2006.03.038.
[2] İ. Hacısalihoğlu, F. Yıldız, A. Çelik, Tribocorrosion behavior of plasma nitrided Hardox steels in NaCl solution, Tribol. Int. 120 (2018) 434–445. https://doi.org/10.1016/j.triboint.2018.01.023.
[3] J. Padgurskas, R. Kreivaitis, R. Rukuiža, V. Mihailov, V. Agafii, et al., Tribological properties of coatings obtained by electro-spark alloying C45 steel surfaces, Surf. Coat. Technol. 311 (2017) 90–97. https://doi.org/10.1016/j.surfcoat.2016.12.098.
[4] A.T. Tabrizi, H. Aghajani, F.F. Laleh, Tribological characterization of hybrid chromium nitride thin layer synthesized on titanium, Surf. Coat. Technol. 419 (2021) 127317. https://doi.org/10.1016/j.surfcoat.2021.127317.
[5] E. Marin, R. Offoiach, M. Regis, S. Fusi, A. Lanzutti, L. Fedrizzi, Diffusive thermal treatments combined with PVD coatings for tribological protection of titanium alloys, Mater. Des. 89 (2016) 314–322. https://doi.org/10.1016/j.matdes.2015.10.011.
[6] V.M.C.A. Oliveira, A.M. Vazquez, C. Aguiar, A. Robin, M.J.R. Barboza, Protective effect of plasma-assisted PVD deposited coatings on Ti-6Al-4V alloy in NaCl solutions, Mater. Des. 88 (2015) 1334–1341. https://doi.org/10.1016/j.matdes.2015.08.158.
[7] Q.Y. Hou, Microstructure and wear resistance of steel matrix composite coating reinforced by multiple ceramic particulates using SHS reaction of Al-TiO2-B2O3 system during plasma transferred arc overlay welding, Surf. Coat. Technol. 226 (2013) 113–122. https://doi.org/10.1016/j.surfcoat.2013.03.043.
[8] M. Ding, N. Sahebgharani, F. Musharavati, F. Jaber, E. Zalnezhad, G.H. Yoon, Synthesis and properties of HA/ZnO/CNT nanocomposite, Ceram. Int. 44 (2018) 7746–7753. https://doi.org/10.1016/j.ceramint.2018.01.203.
[9] S.A. Javadi, S.N. Hokmabadi, A. Taghizadeh Tabrizi, H. Aghajani, Corrosion behavior , microstructure and phase formation of ternary Ni–Ti–Si nano composite synthesised by SHS method, Powder Metall. 64 (2021) 341–350. https://doi.org/10.1080/00325899.2021.1906564.
[10] S.S. Javaherian, H. Aghajani, P. Mehdizadeh, Cu-TiO2 composite as fabricated by SHS method, Int. J. Self-Propag. High-Temp. Synth. 23 (2014) 47–54. https://doi.org/10.3103/S1061386214010051.
[11] A.R. Zurnachyan, S.L. Kharatyan, H.L. Khachatryan, A.G. Kirakosyan, Self-propagating high temperature synthesis of SiC-Cu and SiC-Al cermets: Role of chemical activation, Int. J. Refract. Met. Hard Mater. 29 (2011) 250–255. https://doi.org/10.1016/j.ijrmhm.2010.11.002.
[12] L. Li, Q. Bi, J. Yang, W. Liu, Q. Xue, Fabrication of bulk Al2O3 dispersed ultrafine-grained Cu matrix composite by self-propagating high-temperature synthesis casting route, Mater. Lett. 62 (2008) 2458–2460. https://doi.org/10.1016/j.matlet.2007.12.021.
[13] M.H. Fini, A. Amadeh, Improvement of wear and corrosion resistance of AZ91 magnesium alloy by applying Ni-SiC nanocomposite coating via pulse electrodeposition, Trans. Nonferrous Met. Soc. China. 23 (2013) 2914–2922. https://doi.org/10.1016/S1003-6326(13)62814-9.
[14] H. Pourbagheri, H. Aghajani, SHS-Produced Al–Ti–B Master Alloys: Performance in Commercial Al Alloy, Int. J. Self-Propag. High-Temp. Synth. 27 (2018) 245–254. https://doi.org/10.3103/S1061386218040052.
[15] T.S. Balasubramanian, M. Balakrishnan, V. Balasubramanian, M.A.M. Manickam, Influence of welding processes on microstructure, tensile and impact properties of Ti-6Al-4V alloy joints, Trans. Nonferrous Met. Soc. China. 21 (2011) 1253–1262. https://doi.org/10.1016/S1003-6326(11)60850-9.
[16] M. Ziemnicka-Sylwester, The Cu matrix cermets remarkably strengthened by TiB2 ‘in situ’ synthesized via self-propagating high temperature synthesis, Mater. Des. 53 (2014) 758–765. https://doi.org/10.1016/j.matdes.2013.07.092.
[17] Y. Raghupathy, A. Kamboj, M.Y. Rekha, N.P. Narasimha Rao, C. Srivastava, Copper-graphene oxide composite coatings for corrosion protection of mild steel in 3.5% NaCl, Thin Solid Films. 636 (2017) 107–115. https://doi.org/10.1016/j.tsf.2017.05.042.
[18] S.A.N. Mehrabani, A.T. Tabrizi, H. Aghajani, H. Pourbagheri, Corrosion Behavior of SHS-Produced Cu–Ti–B Composites, Int. J. Self-Propag. High-Temp. Synth. 29 (2020) 167–172. https://doi.org/10.3103/S1061386220030061.
[19] V.V. Kurbatkina, E.I. Patsera, E.A. Levashov, A.N. Timofeev, Self-propagating high-temperature synthesis of single-phase binary tantalum-hafnium carbide (Ta,Hf)C and its consolidation by hot pressing and spark plasma sintering, Ceram. Int. 44 (2017) 4320–4329. https://doi.org/10.1016/j.ceramint.2017.12.024.
[20] Y. Liang, Q. Zhao, Z. Zhang, Z. Lin, L. Ren, Fabrication of bionic composite material using self-propagating high-temperature synthesis in the Cu-Ti-B4C system during steel casting, J. Asian Ceram. Soc. 1 (2013) 339–345. https://doi.org/10.1016/j.jascer.2013.10.004.
[21] Y.A. Sorkhe, H. Aghajani, A. Taghizadeh Tabrizi, Mechanical alloying and sintering of nanostructured TiO2 reinforced copper composite and its characterization, Mater. Des. 58 (2014) 168–174. https://doi.org/10.1016/j.matdes.2014.01.040.
[22] Y.A. Sorkhe, H. Aghajani, A. Taghisadeh Tabrizi, Synthesis and characterisation of Cu–TiO2 nanocomposite produced by thermochemical process, Powder Metall. 59 (2016) 107–111. https://doi.org/10.1179/1743290115Y.0000000020.
[23] G.N. Azari, A.T. Tabrizi, H. Aghajani, Investigation on corrosion behavior of Cu-TiO2 nanocomposite synthesized by the use of SHS method, J. Mater. Res. Technol. 8 (2019) 2216–2222. https://doi.org/10.1016/j.jmrt.2019.01.025.
[24] H. Aghajani, S.A.N. Mehrabani, A.T. Tabrizi, F.H. Saddam, Corrosion and mechanical behavior evaluation of in situ synthesized Cu-TiB2 nanocomposite, Synth. Sinter. 1 (2021) 121–126. https://doi.org/10.53063/synsint.2021.1228.
[25] A.T. Tabrizi, H. Aghajani, H. Saghafian, F.F. Laleh, Correction of Archard equation for wear behavior of modified pure titanium, Tribol. Int. 155 (2021) 106772. https://doi.org/10.1016/j.triboint.2020.106772.

Cited By

Crossref Google Scholar
Wear behavior of self-propagating high-temperature synthesized Cu-TiO2 nanocomposites
Submitted
2021-06-04
Available online
2021-08-22
How to Cite
Aghajani, H., Roostaei, M., Sharif Javaherian, S., Taghizadeh Tabrizi, A., Abdoli Silabi, A., & Farzam Mehr, N. (2021). Wear behavior of self-propagating high-temperature synthesized Cu-TiO2 nanocomposites. Synthesis and Sintering, 1(3), 127-134. https://doi.org/10.53063/synsint.2021.1332

Most read articles by the same author(s)