Optimization of direct reduction in tunnel furnace using different resources of ferrous oxides

  • Sara Ahmadi 1
  • Hossein Nuranian 2
  • 1 Construction and Minerals Research Group, Technology and Engineering Research Center, Standard Research institute, Karaj, Alborz, Iran
  • 2 Ceramic Department, Materials and Energy Research Center, Karaj, Alborz, Iran

Abstract

Nowadays it is highly desired to maximize using of existing resources and recycle waste materials. The by-product of steel being hot rolled is mill scale that disposing of it as waste material has environmental effects. Therefore, the use of mill scale in iron production is economically and environmentally beneficial. In the current work, an attempt has been made to use mill scale and iron concentrate which are not applicable to pelletized, in the reduction process with tunnel kiln for iron manufacturing. Non-coking coal and limestone were utilized as reducing agents. The reluctant to ferrous oxide ratio was kept constant during the reduction tests. The reduction process was carried out in a crucible at 1150 °C. The analyses of the metal Fe content in the reduced samples show that the mill scale can be used successfully in the direct reduction process to produce sponge iron.  In the rolling mill scale-iron pellet, iron concentrate-iron pellet, and iron concentrate-mill scale mixtures, the compositions 70MS-30IP, 70IC-30IP, and 70IC-30MS were optimum. The result of XRD and STA results revealed that the optimal heat treatment setting for reducing utilized ferrous oxide mixtures is 1150 °C for 1 h.

Downloads

Download data is not yet available.
Keywords: Direct reduction, Iron pellet, Iron mill scale, Iron concentrate, Tunnel furnace

References

[1] A. Singh, P. Jain, A study on the accretion formation in DRI kilns and possible ways for its reduction, IOSR J. Mech. Civ. Eng. 12 (2015) 98–103. https://doi.org/10.9790/1684-126598103.
[2] M. Kumar, H. Baghel, S.K. Patel, Reduction and Swelling of Fired Hematite Iron Ore Pellets by Non-coking Coal Fines for Application in Sponge Ironmakin, Miner. Process. Extr. Metall. Rev. 34 (2013) 249–267. https://doi.org/10.1080/08827508.2012.656776.
[3] J. Yang, T. Mori, M. Kuwabara, Mechanism of Carbothermic Reduction of Hematite in Hematite–Carbon Composite Pellets, ISIJ Int. 47 (2007) 1394–1400. https://doi.org/10.2355/isijinternational.47.1394.
[4] J. Aota, L. Morin, Q. Zhuang, B. Clements, Direct reduced iron production using cold bonded carbon bearing pellets Part 1 – Laboratory metallization, Ironmak. Steelmak. 33 (2006) 426–428. https://doi.org/10.1179/174328106X118053.
[5] D. Zhu, V. Mendes, T. Chun, J. Pan, Q. Li, et al., Direct Reduction Behaviors of Composite Binder Magnetite Pellets in Coal-based Grate-rotary Kiln Process, ISIJ Int. 51 (2011) 214–219. https://doi.org/10.2355/isijinternational.51.214.
[6] O.P. Chukwuleke, J. Cai, S. Chukwujekwu, S. Xiao, Shift from coke to coal using direct reduction method and challenges, J. Iron Steel Res. Int. 16 (2009) 1–5. https://doi.org/10.1016/S1006-706X(09)60018-2.
[7] A. Sarangi, B. Sarangi, Sponge Iron Production in Rotary Kiln, New Delhi PHI Learning, Pvt. Ltd. (2011).
[8] L. Lu, J. Pan, D. Zhu, Quality requirements of iron ore for iron production, Iron Ore: Mineralogy, Processing and Environmental Sustainability, Woodhead Publishing. (2015) 475–504. https://doi.org/10.1016/B978-1-78242-156-6.00016-2.
[9] R. Sen, S. Dehiya, U. Pandel, M.K. Banerjee, Utilization of low-grade core for direct reduction of mill scale to obtain of sponge iron: effect of reduction time and particle size, Procedia Earth Planet. Sci. 11 (2015) 8–14. https://doi.org/10.1016/j.proeps.2015.06.003.
[10] K.K. Prasad, H. Shankar Ray, Advances in Rotary Kiln Sponge Iron Plant, New Age International. (2009).
[11] A. Chatterjee, Sponge Iron Production by Direct Reduction of Iron Oxide, Prentice-Hall Of India Pvt Ltd. (2010).
[12] S.C. Khattoi, G.G. Roy, Sponge iron production from ore – coal composite pellets in tunnel kiln, India Iron Production, Project. (2013).
[13] H.A. Mashhadi, A. Rastgoo, J.V. Khaki, An investigation on the reduction of iron ore pellets in fixed bed of domestic non-coking coals, Int. J. Iron Steel Soc. Iran. 5 (2008) 8–14.
[14] N. Toloue Farrokh, M. Askari, T. Fabritius, Behavior of three non-coking coals from Iranian’s deposits in simulated thermal regime of tunnel kiln direct reduction of iron, J. Anal. Appl. Pyrolysis. 123 (2017) 395–401. https://doi.org/10.1016/j.jaap.2016.10.028.
[15] G.S. Upadhyaya, Powder Metallurgy Technology, Cambridge International Science Publishing, Cambridge. (1997).
[16] M.J. Keyser, M. Conradie, M. Coertzen, J.C. Van Dyk, Effect of coal particle size distribution on packed bed pressure drop and gas flow distribution, Fuel. 85 (2006) 1439–1445. https://doi.org/10.1016/j.fuel.2005.12.012.
[17] K. Jouhari, P. Datta, Proceedings of the seminar on experimental approaches in pyrometallurgical research, chapter- Effect of Calcium Carbonate on degree of Reduction in Mill Scale by Coal, Allied Publishers. (2000).
[18] M.I. Martin, F.A. Lopez, M.E. Rabanal, J.M. Torralba, Production of Sponge Iron Powder by Reduction of a by-product of Steel making Industry, PM2010 World congress-Waer Atomized Powders. (2010).
[19] M.I. Martin, F.A. Lopez, M.E. Rabanal, J.M. Torralba, Obtainment of Sponge Iron by Reduction of a by-product, National Conference on Advances Materials Recycling and Eco-Energy. (2009).
[20] O. Benchiheub, S. Mechachti, S. Serri, M.G. Khalifa, Elaboration of Iron powder from Mill Scale, J. Mater. Environ. Sci. 1 (2010) 267–276.
[21] L. Camci, S. Aydin, C. Arslan, Reduction of iron oxides in solid wastes generated by steelworks, Turk. J. Environ. Eng. Sci. 26 (2002) 37–44.
[22] J.-W. Park, J.-C. Ahn, H. Song, K. Park, H. Shin, J.-s. Ahn, Reduction characteristics of oily hot rolling mill sludge by direct reduced iron method, Resour. Conserv. Recycl. 34 (2002) 129–140. https://doi.org/10.1016/S0921-3449(01)00098-2.
[23] A.D. Pelton, C.W. Bale, Direct Reduced Iron: Technology and Economics of Production and Use. Iron & Steel Society, Warrendale. (1999).
[24] V.B. Akimenko, I.A. Gulyaev, M.A. Sekachev, O.Y. Kalashnikova, Reduced Iron powder: Manufacturing problems and Prospects, Steel Transl. 41 (2011) 622–626. https://doi.org/10.3103/S0967091211070023.

Cited By

Crossref Google Scholar
Optimization of direct reduction in tunnel furnace using different resources of ferrous oxides
Submitted
2022-11-25
Published
2023-03-30
How to Cite
Ahmadi, S., & Nuranian, H. (2023). Optimization of direct reduction in tunnel furnace using different resources of ferrous oxides. Synthesis and Sintering, 3(1), 60-66. https://doi.org/10.53063/synsint.2023.31130